基于α-FeOOH催化H2O2蒸气的低温烟气脱硝实验

针铁矿是分布广泛、储量丰富的铁氧化物，其主要成分为α-羟基氧化铁（α-FeOOH）。为了探究针铁矿在催化H₂O₂烟气脱硝反应中的性能，本文通过沉淀-水解法制备了α-FeOOH，并在自行搭建的实验台上开展了α-FeOOH催化H₂O₂的低温烟气脱硝实验研究，深入分析了H₂O₂流量、H₂O₂浓度、汽化温度、反应温度和共存气体浓度等工况参数对脱硝性能的影响。采用离子色谱（IC）分析了单独脱硝反应和同时脱硫脱硝反应后的含氧酸成分，结合各项表征分析技术考察了催化剂反应前后的理化特性和稳定性。实验结果显示，随着汽化温度和反应温度的升高，NO的脱除效率先增加后降低；增加H₂O₂浓度对脱硝效率有明显的促进作用。当汽化温度为140℃、反应温度为160℃时，以2.5mL/h注入10mol/L的H₂O₂脱硝效率达到80%。当SO₂浓度为1000μL/L时，脱硝效率提高至86.4%。离子色谱分析结果显示，单独脱硝反应和同时脱硫脱硝反应后含氧酸产物为HNO₃和H₂SO₄。反应前后催化剂的表征结果显示，α-FeOOH在脱硝反应后依然具有良好的稳定性，显示出针铁矿在低温烟气脱硝工艺中的潜在应用前景。     

A novel temperature-tolerant foamed resin for enhanced oil recovery

The synthesis and performance of a novel temperature-tolerant foamed resin for enhanced oil recovery were investigated using various methods, including infrared, NMR, scanning electron microscopy (SEM), and displacement experiments. Polycondensation of furfuryl alcohol prepolymers was confirmed by the infrared and NMR results. The poor temperature tolerance of furfuryl alcohol prepolymers after gelation at high temperatures is mainly due to the fracture of furan rings. The addition of ester additives is an effective method of increasing the temperature tolerance of the prepared foamed resins and can effectively reduce the weight-loss rate of the polycondensation products. The SEM results show that the skeleton structure of the foamed resin remains intact after high-temperature treatment. Thus, the novel plugging agent system has excellent thermal stability and still has a high strength (>0.8 MPa) after high-temperature aging treatment for 40 days, giving the prepared foamed resin a good plugging performance (plugging rate > 91%) at 250 °C. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47161.     

Deacylation of Calcium-Dependent Antibiotics from Streptomyces violaceoruber in Co-culture with Streptomyces sp. MG7-G1

When Streptomyces violaceoruber grows together with Streptomyces sp. MG7-G1, it reacts with strongly induced droplet production on its aerial mycelium. Initially the metabolite profile of droplets from S. violaceoruber in co-culture with Streptomyces sp. MG7-G1 was compared to samples from S. violaceoruber in single-culture by using high-performance liquid chromatography-mass spectrometry (HPLC-MS). Then, the exudate from agar plates of co-cultures and single cultures (after freezing and thawing) was also analysed. Several compounds were only observed when S. violaceoruber was grown in co-culture. Based on their high-resolution ESI mass spectra and their comparable retention times to the calcium-dependent antibiotics (CDAs) produced by S. violaceoruber, the new compounds were suspected to be deacylated calcium-dependent antibiotics (daCDAs), lacking the 2,3-epoxyhexanoyl residue of CDAs. This was verified by detailed analysis of the MS/MS spectra of the daCDAs in comparison to the CDAs. The major CDA compounds present in calcium ion-supplemented agar medium of co-cultures were daCDAs, thus suggesting that Streptomyces sp. MG7-G1 expresses a deacylase that degrades CDAs.     

Prediction of methane adsorption content in continental coal-bearing shale reservoir using SLD model

Shale gas, as an important unconventional resource, has drawn global attention. It is mainly composed of adsorption gas and free gas. Adsorption gas content could play an important guiding role on both the selection of favorable perspective area and the exploration and exploitation of shale gas resources. In order to accurately measure adsorption gas content, a new approach was established to predict the adsorption isotherm of methane on shale. Based on the simplified local-density (SLD) method, both the adsorption isotherms of illite, illite/smectite mixed-layer, cholorite and type III kerogen and the total shale rock could be well fitted. The fitting results show good coincidences with the true experimental test data, which proves the method is reasonable and dependable and the prediction results are effective and credible. In addition, the good simulation results show that the SLD parameters can reflect the pore structure characteristics and corresponding adsorption characteristics of the shale samples, which can be used for the quantitative characterization of shale pore system.     

枪管结构对固有频率的影响

为了研究枪管结构对枪管固有频率的影响,针对枪管尤其是狙击枪管设计中约束长度、枪管外形、膛口装置以及膛线等不同结构,建立了相应的三维模型。采用以六面体为主的网格对枪管进行了网格划分,采用有限元方法对枪管进行了模态分析。计算获得了不同结构枪管的固有频率; 通过比较,得到了不同枪管结构对固有频率的影响。分析结果表明:枪管尾部螺纹长度越长,枪口振动幅度越低; 相同质量枪管,锥形外形枪管刚度最好; 加装膛口装置对枪管刚度和振动特性有不利影响。     

两种3D打印用雾化Ti-6Al-4V粉末的对比研究

本研究分别利用水冷铜坩埚真空感应熔炼气雾化(VIGA-CC)和等离子旋转电极(PREP)两种技术制备出球形Ti-6Al-4V合金粉末,作者利用SEM、同步辐射CT扫描-三维重建和氩气含量测试等分析手段对不同粒径的Ti-6Al-4V合金粉末的孔洞缺陷和氩气含量、硬度值进行了表征。实验结果表明, VIGA-CC粉末粒度分布宽,细粉收得率较多,粉末粒度分布在40~180 μm之间, PREP粉末的粒度分布较窄,主要集中在110~180 μm之间；金属粉末内部的孔隙率、气体含量和孔尺寸随着粉末粒度的增大而增大,且同一粒径范围内VIGA-CC粉末的气孔概率多于PREP粉末；随着粉末粒径减小,粉末截面组织逐渐细化,其硬度值逐渐升高,整体上VIGA-CC粉末硬度值高于PREP粉末。     

碳酸盐岩岩溶储层多井评价方法及地质应用

多井评价是建立在单井精细解释对比分析基础上的预测储层及含油气性平面分布规律的技术方法,而常规测井资料无法区分碳酸盐岩岩溶储层,因而利用多井评价结果确定岩溶发育程度在平面上的分布规律就显得十分重要。为此,在岩心标定成像测井的基础上,对四川盆地高石梯—磨溪地区15口井的成像测井岩溶发育特征进行分析,建立了中二叠统茅口组岩溶发育各分带的标准成像图版,利用交会图及直方图分析各分带的常规测井响应特征,在此基础上形成了电成像测井刻度常规测井识别岩溶发育带的新方法。研究结果表明:①高石梯—磨溪地区茅口组岩溶带自上而下可划分为风化壳残积带、垂直渗流岩溶带、水平潜流岩溶带以及受岩溶作用较弱的基岩;②风化壳残积带在成像测井图像显示为"暗—亮—暗"条带状模式,垂直渗流岩溶带为垂直线状与暗色斑状组合模式,水平潜流岩溶带为水平线状—层状与斑状组合模式,基岩整体显示为亮色块状模式偶见线状或斑状特征;③有效储层主要发育在垂直渗流带和水平潜流带的顶部;④该区茅口组岩溶发育主要受裂缝发育控制,而裂缝发育又与断层关系密切。结论认为,该新方法对碳酸盐岩岩溶储层的多井评价具有普遍适用性,为四川盆地中二叠统风险探井的部署提供了技术支撑。     

自然循环工况下离心泵阻力特性的实验研究与数值模拟

停转后泵的阻力特性对自然循环流量影响明显。为研究低流量自然循环工况下离心泵的阻力特性，设计了实验台架，对离心泵的正向压降、反向压降和损失系数进行了测量，实验雷诺数为2.0×10⁴～1.5×10⁵。实验表明：相同雷诺数下，反向压降明显高于正向压降；雷诺数大于8×10⁴时，损失系数基本保持不变，而低雷诺数下损失系数随雷诺数的降低有增大的趋势；基于实验得到了损失系数的经验关系式。采用CFD方法对离心泵的内部流场进行了模拟，计算表明：CFD方法能较好地预测损失系数，RNG k-ε模型与实验值的相对误差不超过10%；离心泵的压力损失主要集中在叶轮、导叶等结构的交界区域；正向与反向流动的流场分布存在显著区别；低雷诺数下局部流动更加不稳定。     

气藏型储气库注气期试井分析探讨

针对气藏型储气库注采井注采过程中储层物性参数影响因素不明确、注采能力不对称的问题。基于相国寺储气库井下连续油管试井测试结果,提出储气库注气期“温降效应”、“变表皮效应”的概念,分析了储气库注采过程中温降效应、变表皮效应以及储层应力敏感对注采的影响。通过气藏型储气库注气期试井分析技术,研究各因素在试井曲线上的响应特征以及对试井解释参数的影响。结果表明:①相对于采气期试井测试,注气期测试得到的储层物性参数具有同样的参考价值;②储气库温降效应对于试井解释结果的影响可忽略不计,而在不同注采运行周期内,变表皮效应以及应力敏感效应影响差异较大;③编制储气库注采运行方案时应充分考虑变表皮效应与应力敏感的影响,在不同注采运行周期内开展试井测试获取准确的储层参数值。研究成果为储气库试井测试与解释提供了重要的研究依据和理论指导。     

仪器仪表产品脉冲耐压试验要求和保护器件的选择

仪器仪表产品的脉冲耐压试验是产品型式试验、例行试验中的基本内容。通过对GB4793.1标准的整理,归纳了仪器仪表产品的脉冲耐压试验要求。通过对试验方法和设备特性的梳理,总结了特性参数,并介绍了应对脉冲耐压试验可采取的保护器件的类别及选用方法。